Pyrolysis of Plastic Waste: Yield Analysis for Fuel vs Circular Monomers

Plastic pyrolysis has re-emerged as one of the most hyped waste-to-X routes. But there is a fundamental split between plants designed to make fuels (marine fuels, heating oil) and those targeting "circular" monomers (naphtha-range feedstock for steam crackers). This outlook examines how feedstock mix, operating conditions, and product upgrading shape yields and economics for both pathways.

What You'll Learn

1. Technology Basics: How Plastic Pyrolysis Works

Pyrolysis thermally decomposes long-chain polymers into smaller molecules in an oxygen-free environment. Core elements include:

Fuel-Oriented Pyrolysis

Optimised for high total liquid yield and tolerant of mixed plastics and contaminants. Product quality is aligned with marine or heating fuel specs after hydrotreating.

Circular Monomer Pyrolysis

Targets narrow-boiling naphtha-like fractions suitable for steam cracking. Requires tighter control of feedstock, halogens and metals, and more extensive upgrading.

ESG & Compliance

Recognition as "recycling" vs "recovery" depends on jurisdiction, mass balance rules, and product destination.

2. Feedstock Mix & Contaminants

Real-world plastic waste rarely looks like clean PE pellets. Typical incoming streams include:

Indicative Feedstock Quality Requirements

Parameter Fuel-Oriented Plant Circular Monomer Plant
Polyolefin content (PE+PP) > 60% > 80%
PVC/chlorine content Moderate control with dechlorination Strictly limited (< few 100 ppm Cl) to protect crackers
Metals & inorganics Managed via filtration & char handling Requires tighter spec and more robust pre-treatment

3. Yield Snapshot: Fuel vs Circular Monomer Slates

The same reactor can deliver very different product slates depending on feedstock and operating window. The table below shows illustrative yields for a polyolefin-rich mix.

Indicative Product Yields at 480–520 °C (Polyolefin-Rich Feed)

Product Fuel-Oriented Configuration Circular Monomer Configuration
Condensed liquid (total) ~ 65–70 wt% ~ 55–60 wt%
Naphtha-range fraction ~ 20–25 wt% ~ 35–40 wt%
Non-condensable gas ~ 15–20 wt% ~ 20–25 wt%
Solid residue (char + inorganics) ~ 10–15 wt% ~ 10–15 wt%

Illustrative Product Yields by Configuration

Comparison of liquid, gas and solid yields for fuel-oriented vs circular monomer-oriented plastic pyrolysis.

4. Operating Window: Temperature & Residence Time

Within realistic reactor designs, higher temperatures and longer vapour residence times generally move the slate towards lighter products and more gas:

Liquid vs Gas Yield vs Temperature (Indicative)

Illustrative trend for total liquid and gas yields across a simplified temperature window.

5. Economics: Capex, Opex & Product Value

Economics depend not only on yield but on realised product pricing and upgrading cost:

Simplified Economics for a 40–60 kt/y Plant (Illustrative)

Metric Fuel-Oriented Plant Circular Monomer Plant
Total capex (incl. pre-treatment & upgrading) €80–110 million €100–140 million
Specific capex (€/t input) ~ €2,000–2,700 ~ €2,500–3,500
Indicative EBITDA margin ~ 15–20% ~ 18–25% (where circular premiums apply)

From a system planner’s viewpoint, plastic pyrolysis sits alongside enzymatic PET recycling concepts, WtE incineration routes, and the broader bio-economy & waste-to-X opportunity set when deciding how to handle difficult residual plastic streams.

Revenue Stack: Fuel vs Circular Monomer Pathways

Illustrative €/t input breakdown of revenues for fuel vs circular monomer projects in supportive markets.

6. Routes Comparison: Fuel vs Circular Monomer

Key trade-offs between the two business models:

Case Study – Same Feedstock, Two Offtake Strategies

Consider a 50 kt/y feedstock base composed of 80% polyolefins and 20% other plastics and residues:

Under strong circular demand, the second route can achieve higher average realised value per tonne, but with more complex contracting and quality management.

7. Devil's Advocate: Technology & ESG Risks

Despite heavy marketing, plastic pyrolysis is not risk-free:

For institutional capital, the most bankable projects are those with strong technology references, conservative yield assumptions, and robust offtake contracts that clearly define specs, pricing and allocation of operational risks.

8. Outlook to 2030: Where Will Capital Flow?

By 2030, we expect:

Pyrolysis is unlikely to "solve" plastic waste alone, but it can be a valuable tool for handling fractions that are not mechanically recyclable, if deployed with realistic expectations and transparent reporting.

Frequently Asked Questions

Is plastic pyrolysis counted as recycling or energy recovery?

It depends on the jurisdiction and on where the products end up. Fuel-heavy projects are often treated closer to energy recovery, while projects supplying cracker feedstocks under recognised mass-balance schemes have a stronger claim to be counted as "recycling".

What is the main technical risk in scaling up plastic pyrolysis?

The biggest risk is achieving stable operation with heterogeneous, contaminated real-world feedstock, including PVC, multilayers and additives. This affects reactor performance, fouling, and downstream upgrading units.

How should investors look at fuel vs circular monomer projects?

Investors should examine offtaker quality, contract structure, product pricing formulas, and policy alignment. Circular monomer projects may offer higher upside but usually come with stricter specs and closer integration with a small number of petrochemical partners.

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